小兴凯湖表层底泥磷吸附容量及潜在释放风险
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2020-02-27 13:09:23
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中国环境科学2014,34(8):2078~2085ChinaEnvironmentalScience小兴凯湖表层底泥磷吸附容量及潜在释放风险于淑玲,李晓宇,张继涛,陈国双,李秀军(1.中国科学院湿地生态与环境重点实验室,中国科学院东北地理与农业生态研究所,吉林长春130102;2.中国科学院大学,北京100049)摘要:利用沉积物磷吸附指数(PsI)和磷吸附饱和度(DPs)研究了小兴凯湖表层沉积物的磷吸附容量,分析了沉积物中磷的吸附饱和度(DPS)与其他指标的相关关系,并讨论了不同采样点湖泊沉积物中磷的潜在释放风险.结果表明:13个采样点的表层沉积物的PSI为9.78~197.53(rag·L)/(1OOg·0too1),平均值为59.77(mg·L)/(100g·~mo1);DPS为9.95~/~24.47%,平均值为15.41%.PSI与草酸铵提取的磷(P0)极显著正相关,与草酸铵提取的铁、铝(Fe,A10x)显著正相关,草酸铵提取的铁是影响PSI的主导因素;DPS主要受沉积物中原有吸附态磷的影响.此外,磷释放风险指数(Em)8.99%~129.94%的计算结果表明_,J、兴凯湖表层沉积物中磷释放诱发富营养化的风险处于高度风险范围,其中,受农业面源污染影响较大的北岸区域相比其他区域发生富营养化的风险更高.关键词:磷吸附指数;磷吸附饱和度;富营养化风险;铁铝氧化物;小兴凯湖中图分类号:X524,X142文献标识码:A文章编号:1000—6923(2014)08—2078—08PhsophorussorptioncapacityofsurfacesedimentsandriskassessmentofpotentialphosphorusreleaseinLakeXiaoxingkai,China.YUShu.1ing,,LIXiao.yu,ZHANGJi.tao,CHENGuo.shuang,LIXiu~un(1.KeyLaboratoryofWetlandEcologyandEnvironment,NortheastInstituteofGeographyandAgroecology,ChineseAcademyofSciences,Changchun130102,China;2.UniversityofChineseAcademyofSciences,Beijing100049,China).ChinaEnvironmentalScience,2014,34(8):2078-2085Abstract:Phosphorussorptioncapacityofsurfacesedimentsareestimatedbyphosphorussorptionindex(PSI)ofsedimentsanddegreeofphosphorussaturation(DPS)inLakeXiaoxingkai,China.TherelationshipbetweenDPSandotherindicatorswereanalyzed,andtheriskofpotentialphosphorusreleasewerediscussedbycalculatingphosphorusreleaseriskindex(ERI).TheresultsshowedthatPSIrangedfrom9.78to197.53(mgL)/(100g’gmo1),withanaverageof59.77(mg’L)/(100g-gtmo1).DPSrangedfrom9.95%to24.47%.withanaverageof15.41%.PS1wassignificantlyandpositivelyco.elatedtophosphorus(P0x),iron(Fe0x)andaluminum(Alox)extractedfromsedimentbyammoniumoxalate.RionextractedfromsedimentbyammoniumoxalatemightbethemainfactortoafectPSI.DPSWasinfluencedmainlybyoriginaladsorbedphosphorusofsediments(orPox).Inaddition,ERIrangedfrom8.99%to129.94%,whichindicatedthattheLakeXiaoxingkaimightbeinhighpotentialeutrophicationriskduetothereleaseofphosphorusfromsurfacesediments.Comparedtothediferentsamplepoints,th
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