I
- 污水草根
-
29 次阅读
-
0 次下载
-
2019-03-30 09:36:22
文档简介:
IIlkovičequation345●IIIcebergstructure—Watermoleculesadjacenttoanor-ganic(nonpolar)liquidorsolidphaseandalsoadjacenttosinglehydrophobicmoleculesorhydrophobicpartsofmoleculesareformingashell-likestructureviahydro-genbonding.FrankandEvans[i]havecalledthis‘ice-bergstructure’becauseofitssimilaritywiththestructureofice.Thisstructurebuildingisassociatedwithalossofentropy,andthereforethateffectispartiallyresponsi-bleforthelowsolubilityofnonpolarliquidsinwater,for�micelleformation,proteinfolding,etc.[ii].Seealso�hydrophobiceffect.Refs.:[i]FrankHS,EvansMW()JChemPhys:;[ii]TanfordC(,ndedn.)Thehydrophobiceffect:formationofmicellesandbiologicalmembranes.Wiley,NewYorkFSIdealnonpolarizableelectrode—Anelectrodewhosepotentialdoesnotchangeuponpassageofthecur-rent.Typicalsuchelectrodeswithfixedpotentialarethe�referenceelectrodes.Seealso�electrode.Ref.:[i]BardAJ,FaulknerLR()Electrochemicalmethods,nded.Wiley,NewYork,pJLIdealdepolarizedelectrode—Workingelectrodeinthesituation,whenel
评论
发表评论